Nespoli, Russian cosmonaut Dmitry Kondratyev and NASA astronaut Cady Coleman were departing the station for a return to Earth after five months on the station.
Nespoli documented the station from a distance of 600 feet as it was rotated 130 degrees.
The chance to snap a Shuttle docked at the ISS from a nearby spacecraft had not arisen before, and won't again with the Shuttle era now almost over.
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